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@Article{SouzaLinaFerrLanz:2022:UsHyCo,
                title = "Using Hybrid Coupling Processes for the Treatment of Waste 
                         Containing Halosulfuron-Methyl Herbicide",
               number = "11",
           targetfile = "ChemElectroChem - 2022 - Souza - Using Hybrid Coupling Processes 
                         for the Treatment of Waste Containing 
                         Halosulfuron\‐Methyl.pdf",
                pages = "e202200221",
               volume = "9",
             keywords = "Fenton, hydrogen peroxide, UV lightboron-doped diamond, Halomethyl 
                         sulfuron.",
             abstract = "This work aims to demonstrate the importance of coupling different 
                         degradation processes for the removal of the commercial herbicide 
                         Halosulfuron-Methyl (HSM). Using anode oxidation (AO) on 
                         boron-doped diamond as the base process; cathodically produced 
                         H2O2 (AO/H2O2), UV light (AO/UV), AO/UV/H2O2, electro-Fenton and 
                         photoelectron Fenton (PEF) are employed as hybrid processes for 
                         HSM degradation. All hybrid processes employed in the study 
                         exhibited synergism with AO, and the UV-irradiated processes 
                         presented an outstanding performance. In particular, the 
                         AO/UV/H2O2 process exhibited 90 % mineralization after 3 h of 
                         treatment, whereas the PEF process exhibited a complete removal of 
                         HSM after 45 min of treatment. In addition to the noticeable 
                         advantages of hybridization, the application of higher current 
                         densities is found to accelerate the degradation/mineralization of 
                         the compound of interest, although the process tends to be more 
                         energy demanding. In such a case, the use of a hybrid treatment 
                         process coupled to UV-irradiation allows one to mitigate this 
                         constraint while contributing toward obtaining higher 
                         mineralization degrees. The degradation/mineralization of more 
                         concentrated solutions is, however, found to occur more sluggishly 
                         under the treatment mechanisms investigated here, requiring longer 
                         times, although the process is noticeably more efficient in 
                         photo-irradiated processes, which recorded current efficiencies of 
                         above 100 %.",
                  doi = "10.1002/celc.202200221",
                  url = "http://dx.doi.org/10.1002/celc.202200221",
               author = "Souza, Fernanda L. and Linares, Jos{\'e} J. and Ferreira, 
                         Neiden{\^e}i Gomes and Lanza, Marcos R. V.",
                month = "June",
          affiliation = "{Universidade Federal de S{\~a}o Carlos (UFSCar)} and 
                         {Universidade de Bras{\'{\i}}lia (UnB)} and {Instituto Nacional 
                         de Pesquisas Espaciais (INPE)} and {Universidade Federal de 
                         S{\~a}o Carlos (UFSCar)}",
              journal = "Chemelectrochem",
             language = "en",
                 year = "2022",
        urlaccessdate = "2022, July 07"
}


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